I used a little alcohol on a q-tip and applied just enough to the edge of the button that capillary action took some of the liquid between the button and screen surface without dripping any into the iPod itself.
Next, I cut a strip of very sticky tape (book tape) to the width of the button and about an inch long, trimmed it round at one end and stuck it to the button. Tape extending past the button (i.e. not directly over the button) was covered with paper so the tape only sticks to the button. With this long leader attached to the button, I held it in place with my thumb and ROTATED the tape (rotating the button along with it.) After a few turns, whatever dirt was holding the button in place was loosened and the button popped back out again. Now the button works perfectly.
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I experienced this problem and the answers here were a great help! If you can't access Settings because your home button is gone/does not work, use a notification from the lock screen to open a program on the iPod, then ask Siri to turn on Settings. From there you can then turn on Assistive Touch and use that as your home button. This saved me from having to replace my iPod!
crwdns2934271:0crwdnd2934271:0 Ami Bebbington crwdne2934271:0