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The following guide will allow you to remove makeup stain from any piece of clothing, but more specifically cotton shirts and tops. Please proceed with caution for expensive clothing. For larger or stronger stains, use larger amounts of cleaning products. In addition, please be aware of delicate fabrics and dry-clean only market clothing as they require special treatments done by professionals. You may also take a look at this article from Glamour magazine that gives a couple of different ways to remove makeup stain from clothing.
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Place a white napkin or rag under the shirt to avoid making a mess or colour transfer into the garment.
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Pat the stain dry with the napkin/rag from Step 1.
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Wash the shirt in cold water with the detergent of your choice.
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Pour detergent over the stain. Pour baking soda or powder over the soap.
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Scrub the paste into the shirt with a toothbrush.
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Wash the shirt in cold water followed by lukewarm water.
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Let the shirt air dry and iron it if necessary.
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Let the shirt air dry and iron as needed.
Let the shirt air dry and iron as needed.